The separation of grain and grain boundary impedance in thin yttria stabilized zirconia (YSZ) layers
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چکیده
منابع مشابه
Oxygen reduction via grain boundary transport in thin film platinum electrodes on yttria stabilized zirconia
Model-type sputter deposited platinum microelectrodes with different grain sizes were investigated on single crystalline yttria stabilized zirconia (YSZ) by means of impedance spectroscopy. Measurements on single platinum microelectrodes could be continuously performed for > 100 h and from 250 to 800 °C without losing contact. From the temperature dependence, two parallel reaction pathways for ...
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,]u amlll'slS tS prt 'seulud o / gralu ,t~lO111/i tllld th'll,~l~COtl/m o/ r t t r la-cr l lo ,~_taluh:t'd tetlagOlla/ .llT'Ollltl Imlrcrrstal,~ ' ( ] ' , ( ' e ' I 'ZPs) u,~'lllg both i,~'/~thrrllla[ alld IlOll-I,~'otllerllla/ Icl']llllqllr,~ T/lu ch/Ir tl¢'lt'rlSlll'S O/ )', Ct' 'I~ZP.~ ' or'(' i'olup, lred 11/ thosr o/ )'. F Z f ' uud C~'. T'Z[' aud the 1'/-/('('t o/lul'r/'a,~lu,t~ i'~'l'lU ...
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Yttria-stabilized zirconia (YSZ) is one of the primary choices for the electrolyte material in solid oxide fuel cells (SOFC), due to its excellent ionic conductivity at high temperatures. Nevertheless, such performance is usually limited by the ionic conductivity at grain boundaries, which is at least two orders of magnitude lower than that of bulk [1]. As a result, many studies have been perfo...
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Yttria-stabilized zirconia (YSZ) is one of the primary choices for the electrolyte material in solid oxide fuel cells (SOFC), due to its excellent ionic conductivity at high temperatures. Nevertheless, such performance is usually limited by the ionic conductivity at grain boundaries, which is at least two orders of magnitude lower than that of bulk [1]. As a result, many studies have been perfo...
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ژورنال
عنوان ژورنال: Solid State Ionics
سال: 2011
ISSN: 0167-2738
DOI: 10.1016/j.ssi.2011.01.008